Xavi Hernandez unlocked Mallorca's defense with a free kick in the 28th minute before Messi st0ruck in the 44th. Cristian Tello added a third goal a minute later at Iberostar stadium on Sunday.
After Mallorca netted twice early in the second half to breathe life into the match, Messi stepped up to score again the 70th to ensure victory as Barcelona rebounded from its loss at Celtic in the Champions League.
"Leo's records are spectacular" said Barcelona coach Tito Vilanova. "It's spectacular when you think that he scores so many goals. Some few players reach these numbers in seven or eight seasons, he does it in one. And most of his goals are great goals."
This is the latest scoring feat for the Argentina forward, one of the leading candidates for the Ballon D'Or. Messi scored 73 goals in the 2011-12 season for Barcelona, breaking the previous European club record of 67 goals set by Mueller in 1972-73.
He also set a Spanish league record of 50 goals last season and broke Cesar Rodriguez's 57-year milestone of 232 goals to become Barcelona all-time leading scorer. Barcelona's 10th win in 11 rounds extended its club-record start and opened up a provisional 11-point gap over third-place Madrid ahead of its game at Levante.
Also, second-place Atletico Madrid stayed three points behind the pacesetters by easing past visiting Getafe 2-0 thanks to goals by Adrian Lopez and Arda Turan. Joaquin Caparros' Mallorca tried to follow Celtic's defensive blueprint from Wednesday's upset in Glasgow. But the strategy didn't last even half an hour.
Xavi Hernandez took full advantage of a foul earned by Cesc Fabregas on the edge of the area. The Spain midfielder bent a beautiful free kick over the defensive barrier that turned goalkeeper Dudu Aouate into yet another spectator as it fell into his net.
"Both Xavi's opener and Leo's goal to make it 4-2 were the turning points to the match," said Gerard Pique, who made his first start for Barcelona since injuring his foot in September. Messi converted Barcelona's 75 percent of possession into a deserved second goal when the Argentina forward dribbled by several defenders and unleashed a left footed-shot that Aouate let slip through his hands.
Tello then quickly made it 3-0 by curving a strike from outside the area into the far side of the goal. When it appeared Barcelona would cruise to the comfortable victory, two errors allowed Mallorca to get back into the game.
Mallorca's Michael Pereira pulled one back in the 55th after Javier Mascherano lost the ball. Two minutes later, Victor Casadesus made it 3-2 from the penalty spot following Sergio Busquets' handball in the box.
But Messi received a chested pass from Alexis Sanchez and smashed the ball into the top corner to restore Barcelona's two-goal advantage and crush Mallorca's hopes. Messi's seventh double of the season increased his league-leading tally to 15 goals. He has 20 in all competitions this season.
Pele scored 75 goals for Brazil and Santos in 1958. Mueller had 85 in 1972 for West Germany and Bayern Munich.
Elsewhere on Sunday, Athletic Bilbao beat visiting Sevilla 2-0 for its first back-to-back wins of the season, while 10-man Valencia stayed winless away this season after drawing 1-1 at Valladolid.
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